positronium 0.1.6

python tools pertaining to positronium

# positronium
python tools pertaining to positronium

## Prerequisites

Tested using Anaconda (Continuum Analytics) with Python 2.7 and 3.5. Examples written using IPython 4.0.1 (python 3.5.1 kernel).

Package dependencies:

* scipy

IPython examples dependencies:

* numpy
* matplotlib

## Installation

via pip (recommended):

```
pip install positronium
```

alternatively, try the development version

```
git clone https://github.com/PositroniumSpectroscopy/positronium
```

and then run

```
python setup.py install
```


## About

This package is designed to collate useful bits of code relating to the positronium atom
(an electron bound to its antiparticle, the positron). The functions are generally simple
approximations that give roughly the right answers, rather than rigorous quantum mechanical
calculations.

The package currently only contains a few very simple modules.

### constants

is intended to collect useful constants in SI units, including:

|const | description |
|-----------|----------------------------------------------------------|
|m_Ps | 2 * mass_electron |
|Rydberg_Ps | Rydberg value for Ps |
|a_Ps | Bohr radius for Ps |
|decay_pPs | decay rate of para-Ps |
|decay_oPs | decay rate of ortho-Ps |
|tau_pPs | lifetime of n=1 para-Ps |
|tau_oPs | lifetime of n=1 ortho-Ps |
|nu_hfs | frequency of the ground-state hyperfine splitting |
|energy_hfs | energy interval of the ground-state hyperfine splitting |
|nu_1s2s | frequency of the 1s2s transition |
|energy_1s2s| energy interval of the 1s2s transition |

Example usage,

```python
>>> from positronium.constants import tau_oPs, nu_hfs
>>> print("The mean lifetime of ortho-Ps is", "%.1f ns."%(tau_oPs * 1e9))
The mean lifetime of ortho-Ps is 142.0 ns.

>>> print("The ground-state hyperfine splitting is", "%.1f GHz."%(nu_hfs * 1e-9))
The ground-state hyperfine splitting is 203.4 GHz.
```

Where appropriate constants are stored in a subclass of float called MeasuredValue, which
has a few extra attributes [uncertainty, unit, source, url], for example

```python
>>> tau_oPs
1.4203738423953184e-07

>>> tau_oPs.uncertainty
3.631431333889514e-11

>>> print(tau_oPs.source)
R. S. Vallery, P. W. Zitzewitz, and D. W. Gidley (2003) Phys. Rev. Lett. 90, 203402

>>> tau_oPs.article()
```

The final line opens a url to the source journal.

### Bohr

contains an adaptation of the Rydberg formula, which is used to calculate the principle
energy levels of positronium, or the interval between two levels. The default unit is 'eV',
however, this can be changed using the keyword argument 'unit'.

For instance, the UV wavelength (in nm) needed to excite the Lyman-alpha transition can be found by:

```python
>>> from positronium import Bohr
>>> Bohr.energy(1, 2, unit='nm')
243.00454681357735
```

This accepts numpy arrays for the initial (n1) and/ or final (n2) energy level, e.g.,

```python
>>> import numpy as np
>>> n1 = np.arange(1, 10)
>>> np.array([n1, Bohr.energy(n1, unit='eV')]).T
array([[ 1. , 6.8028465 ],
[ 2. , 1.70071163],
[ 3. , 0.75587183],
[ 4. , 0.42517791],
[ 5. , 0.27211386],
[ 6. , 0.18896796],
[ 7. , 0.1388336 ],
[ 8. , 0.10629448],
[ 9. , 0.08398576]])
```

### Ferrell

contains an equation described in

> Richard A. Ferrell (1951) Phys. Rev. 84, 858
> http://dx.doi.org/10.1103/PhysRev.84.858

which can be used to estimate the energy levels of positronium, including fine structure, but not including radiative corrections.

### Ps

is used to define a class called Ps, which can be used to represent a particular quantum state
of positronium using the quantum numbers

| | |
|-----|--------------------------|
| n | principle |
| l | orbital angular momentum |
| m | magnetic quantum number |
| S | total spin |
| J | total angular momentum |

Class methods can be used to return estimates of, e.g., the energy level, for example

```python
>>> from positronium import Ps
>>> x1 = Ps(n=2, l=1, S=1, J=2)
>>> x1.energy(unit='eV')
-1.7007156827724967
```

or to give a representation of the state using Latex code,

```python
>>> x1.tex()
'$2^{3}P_{2}$'
```

For further examples see the IPython/ Jupyter notebooks,

https://github.com/PositroniumSpectroscopy/positronium/tree/master/examples